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pd_proNo:568719-93e39b18-2c6f-414f-a8cc-a2b3689a7c74
pd_productuse:
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Preparation |
Prepared in a patented process by degradation of beta-carotene in the presence of nitrogen and air. |
InChI:InChI=1/C11H16O2/c1-10(2)5-4-6-11(3)8(10)7-9(12)13-11/h7H,4-6H2,1-3H3
Synthesis of natural products has speede...
An improved synthesis of (+/-)-aeginetol...
Carotenoids are reported to have immunol...
In the presence of a Cu(I) catalyst and ...
A new, short total synthesis of dihydroa...
all-trans-retinoic-acid
(+/-)-dihydroactinidiolide
(E)-β-ionone
2,6,6-trimethylcyclohex-1-enecarbaldehyde
2E,4E-2-methyl-6-oxo-2,4-heptadienal
4-ethoxyretinoic acid
trans-5,8-epoxy-5,8-dihydroretinoic acid
| Conditions | Yield |
|---|---|
|
With
oxygen;
In
ethanol; water;
at 85.5 ℃;
for 8h;
under 760 Torr;
Product distribution;
Kinetics;
Thermodynamic data;
ΔE(excit.); different ratios of O2, solvent, reaction times and temperatures;
|
(2,6,6-trimethylcyclohex-1-enyl)acetic acid
(+/-)-dihydroactinidiolide
| Conditions | Yield |
|---|---|
|
With
diphenyl diselenide; tetraethylammonium bromide; water; sodium carbonate;
In
acetonitrile;
for 0.6h;
Ambient temperature;
electrolysis under a constant current 70 mA;
|
92% |
4,4,7a-trimethylhexahydro-1-benzofuran-2(3H)-one
(+/-)-aeginetolide
(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
(2,6,6-trimethylcyclohex-1-enyl)acetic acid
C11H20O2
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