Cinnamyl propionate

Available forms:

pd_proNo:531346-04b7cde5-538f-4415-ad56-f52eac40e5dd

pd_productuse:

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Detailed introduction

Factory supply Cinnamyl propionate 103-56-0 with sufficient stock and high standard

  • Molecular Formula:C12H14O2
  • Molecular Weight:190.242
  • Vapor Pressure:0.00136mmHg at 25°C 
  • Refractive Index:n20/D 1.535(lit.)  
  • Boiling Point:297.4 °C at 760 mmHg 
  • Flash Point:131.3 °C 
  • PSA:26.30000 
  • Density:1.037 g/cm3 
  • LogP:2.65300 

Cinnamyl propionate(Cas 103-56-0) Usage

Preparation

By direct esterification of cinnamic alcohol with propionic acid under azeotropic conditions, or with propionic anhydride (Arctander, 1969).

Flammability and Explosibility

Notclassified

Safety Profile

Moderately toxic by ingestion. A skin irritant. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.

Taste threshold values

Taste characteristics at 10 ppm: sweet, floral, waxy, balsamic, green, punch, grape and cherry.

InChI:InChI=1/C12H14O2/c1-2-12(13)14-10-6-9-11-7-4-3-5-8-11/h3-9H,2,10H2,1H3/b9-6+

103-56-0 Relevant articles

Palladium-Catalyzed Three-Component Coupling Reaction of Allyl Carboxylates, Norbornenes and Diboronates Involving Sequential Olefins Insertion and Borylation Reaction

Li, Zun,Zheng, Jia,Li, Chunsheng,Wu, Wanqing,Jiang, Huanfeng

, p. 140 - 147 (2019)

An efficient Pd-catalyzed three-componen...

Efficient Enzymatic Preparation of Flavor Esters in Water

Perdomo, Igor Chiarelli,Gianolio, Stefania,Pinto, Andrea,Romano, Diego,Contente, Martina Letizia,Paradisi, Francesca,Molinari, Francesco

, p. 6517 - 6522 (2019/06/20)

A straightforward biocatalytic method fo...

Cinnamyl alcohol fatty acid ester derivative and application and preparation method thereof

-

Paragraph 0040; 0041, (2019/05/08)

The invention relates to a derivative an...

Synthesis of α-(Pentafluorosulfanyl)- and α-(Trifluoromethyl)-Substituted Carboxylic Acid Derivatives by Ireland-Claisen Rearrangement

Dreier, Anna-Lena,Beutel, Bernd,Mück-Lichtenfeld, Christian,Matsnev, Andrej V.,Thrasher, Joseph S.,Haufe, Günter

, p. 1638 - 1648 (2017/02/10)

Earlier studies have shown that [3,3]-si...

103-56-0 Process route

cinnamyl 2-bromopropanoate
40630-85-1

cinnamyl 2-bromopropanoate

cinnamyl propionate
78761-38-3,103-56-0

cinnamyl propionate

2-methyl-3-phenyl-pent-4-enoic acid
256663-37-3

2-methyl-3-phenyl-pent-4-enoic acid

Conditions
Conditions Yield
cinnamyl 2-bromopropanoate; With tetrahydrofuran; 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; indium(III) chloride; indium; chloro-trimethyl-silane; triethylamine; at 10 - 30 ℃; for 4h; Inert atmosphere; Sonication;
With water; ammonium chloride; In tetrahydrofuran; 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; optical yield given as %de; Saturated solution;
84%
16%
cinnamyl 2-bromopropanoate; With tetrahydrofuran; indium(III) chloride; indium; chloro-trimethyl-silane; triethylamine; at 10 - 30 ℃; Inert atmosphere; Sonication;
With water; ammonium chloride; In tetrahydrofuran; optical yield given as %de; Saturated solution;
68%
32%
3-Phenylpropenol
104-54-1

3-Phenylpropenol

propionic acid
802294-64-0,79-09-4

propionic acid

cinnamyl propionate
78761-38-3,103-56-0

cinnamyl propionate

Conditions
Conditions Yield
With cerium(IV) trifluoromethanesulfonate; at 25 ℃; for 0.5h;
90%
With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 20 ℃; Inert atmosphere;
89%
With sodium tetrahydroborate; Yield given. Multistep reaction; 2) 85 deg C to 90 deg C, 3 h;
With dmap; S,S'-bis(1-phenyl-1H-tetrazol-5-yl) dithiocarbonate; triethylamine; Yield given. Multistep reaction; 1.) ethyl acetate, 0 deg C, 30 min; 2.) room temp., 24 h;

103-56-0 Upstream products

  • 104-54-1
    104-54-1

    3-Phenylpropenol

  • 802294-64-0
    802294-64-0

    propionic acid

  • 40630-85-1
    40630-85-1

    cinnamyl 2-bromopropanoate

  • 105-37-3
    105-37-3

    Ethyl propionate

103-56-0 Downstream products

  • 256663-37-3
    256663-37-3

    2-methyl-3-phenyl-pent-4-enoic acid

  • 101-82-6
    101-82-6

    2-Benzylpyridine

  • 5191-54-8
    5191-54-8

    2-benzyl-4-methyl pyridine

  • 10131-46-1
    10131-46-1

    2-benzyl-6-methylpyridine

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