Nonyl aldehyde

Available forms:brown liquid

pd_proNo:364044-61ad21dd-0e97-454d-bf40-5e3322628321

pd_productuse:

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Detailed introduction

Factory Supply industrial standard Nonyl aldehyde 124-19-6 In Stock

  • Molecular Formula:C9H18O
  • Molecular Weight:142.241
  • Appearance/Colour:brown liquid 
  • Vapor Pressure:0.532mmHg at 25°C 
  • Melting Point:-18oC 
  • Refractive Index:n20/D 1.424(lit.)  
  • Boiling Point:190.778 °C at 760 mmHg 
  • Flash Point:63.889 °C 
  • PSA:17.07000 
  • Density:0.816 g/cm3 
  • LogP:2.93590 

1-Nonanal(Cas 124-19-6) Usage

Safety Profile

A severe skin irritant.Combustible liquid. Mutation data reported. When heatedto decomposition it emits acrid smoke and irritatingfumes.

InChI:InChI=1/C9H18O/c1-2-3-4-5-6-7-8-9-10/h9H,2-8H2,1H3

124-19-6 Relevant articles

Hydroformylation of internal olefins to linear aldehydes with novel rhodium catalysts

Van Der Veen, Lars A.,Kamer, Paul C.J.,Van Leeuwen, Piet W. N. M.

, p. 336 - 338 (1999)

Unprecedented high activities and select...

Diastereoisomeric bisphosphite ligands in the hydroformylation of octenes: Rhodium catalysis and HP-NMR investigations

Selent, Detlef,Baumann, Wolfgang,Wiese, Klaus-Diether,Boerner, Armin

, p. 6203 - 6205 (2008)

Diastereoisomeric hydroformylation catal...

Efficient hydroformylation in dense carbon dioxide using phosphorus ligands without perfluoroalkyl substituents

Koeken, Ard C. J.,Benes, Nieck E.,Van Den Broeke, Leo J. P.,Keurentjes, Jos T. F.

, p. 1442 - 1450 (2009)

Rhodium catalysts modified with tripheny...

Octene hydroformylation by using rhodium complexes tethered onto selectively functionalized mesoporous silica and in situ high pressure IR study

Song, Ki-Chang,Baek, Ji Yeon,Bae, Jung A,Yim, Jin-Heong,Ko, Young Soo,Kim, Do Heui,Park, Young-Kwon,Jeon, Jong-Ki

, p. 561 - 565 (2011)

SBA-15-based heterogeneous catalysts wer...

Magnetically separable chicken feathers: A biopolymer based heterogeneous catalyst for the oxidation of organic substrates

Patnam, Padma L.,Bhatt, Mukesh,Singh, Raghuvir,Saran, Sandeep,Jain, Suman L.

, p. 60888 - 60895 (2016)

Magnetically separable poultry chicken f...

A facile method for promoting activities of ordered mesoporous silica-anchored Rh-P complex catalysts in 1-octene hydroformylation

Zhou, Wei,He, Dehua

, p. 1146 - 1154 (2009)

This work deals with the promotion of im...

Rhodium-catalyzed biphasic hydroformylation of 4-octene using water-soluble calix[4]arene-phosphine ligands

Shirakawa,Shimizu,Sasaki

, p. 777 - 779 (2001)

The hydroformylation of water-insoluble ...

-

Goosen,Laue

, p. 383 (1969)

-

Hydroformylation activity of multinuclear rhodium complexes coordinated to dendritic iminopyridyl and iminophosphine scaffolds

Antonels, Nathan C.,Moss, John R.,Smith, Gregory S.

, p. 2003 - 2007 (2011)

The synthesis of poly(propyleneimine)-im...

Room-temperature production of bio-based aldehydes from vegetable oil-derived epoxide: via H2WO4?Al-MCM-41 as recyclable catalyst

Peng, Libo,Xie, Qinglong,Nie, Yong,Liu, Xuejun,Lu, Meizhen,Ji, Jianbing

, p. 23061 - 23070 (2019)

The oxidative cleavage of vegetable oils...

TEMPO oxidations with a silica-supported catalyst

Bolm, Carsten,Thomas, Fey

, p. 1795 - 1796 (1999)

Silica-supported 1-hydroxy-2,2,6,6-tetra...

Mediated electrolysis of vicinal diols by neocuproine palladium catalysts

Lybaert,Tehrani, K. Abbaspour,De Wael

, p. 685 - 691 (2017)

Synthetic electrochemistry agrees well w...

Hydroformylation of 1-octene in the presence of cobalt alkylidynecarbonyl clusters

Tsoy, A. A.,Korneeva, G. A.,Kayumov, F. F.,Grudtsyn, Yu. D.,Slivinskii, E. V.,et al.

, p. 1320 - 1326 (1993)

The hydroformylation of 1-octene in the ...

Reactivity of platinum stanna-closo-dodecaborate complexes: First hydroformylation studies

Wesemann, Lars,Hagen, Siegbert,Marx, Thiemo,Pantenburg, Ingo,Nobis, Markus,Driessen-Hoelscher, Birgit

, p. 2261 - 2265 (2002)

The synthesis and characterization of tw...

Pd(II) loaded on diamine functionalized LDH for oxidation of primary alcohol using water as solvent

Sahoo, Mitarani,Parida

, p. 36 - 45 (2013)

Hybrid inorganic-organic materials which...

Highly regioselective and active Rh-2,2′-bis(dipyrrolylphosphinooxy)- 1,1′-(±)-binaphthyl catalyst for hydroformylation of 2-octene

Liu, Wenjing,Yuan, Maolin,Fu, Haiyan,Chen, Hua,Li, Ruixiang,Li, Xianjun

, p. 596 - 597 (2009)

Rhodium catalyst bearing 2,2′-bis(dipyrr...

Integration of a phosphine ligand into an ionic liquid: A highly effective biphasic system for the Rh-catalyzed hydroformylation of 1-octene

Jin, Xin,Feng, Jianying,Ma, Qingqing,Song, Hongbing,Liu, Qiangqiang,Xu, Bingying,Zhang, Mei,Li, Shumei,Yu, Shitao

, p. 3267 - 3275 (2019)

In classical biphasic ionic liquid (IL) ...

Heterometallic catalysts. Cobalt carbonyl derivatives of lanthanides in catalysis of octene-1 hydroformylation

Beletskaya, I.P.,Magomedov, G.K.-I.,Voskoboinikov, A.Z.

, p. 289 - 295 (1990)

The results of an investigation involvin...

Rhodium catalysed hydroformylation of alkenes using highly fluorophilic phosphines

Adams, Dave J.,Bennett, James A.,Cole-Hamilton, David J.,Hope, Eric G.,Hopewell, Jonathan,Kight, Jo,Pogorzelec, Peter,Stuart, Alison M.

, p. 3862 - 3867 (2005)

Highly fluorophilic phosphines incorpora...

Realistic energy surfaces for real-world systems: An IMOMO CCSD(T):DFT scheme for rhodium-catalyzed hydroformylation with the 6-dppon ligand

Gellrich, Urs,Himmel, Daniel,Meuwly, Markus,Breit, Bernhard

, p. 16272 - 16281 (2013)

The hydroformylation of terminal alkenes...

Alkylated polyethyleneimine/polyoxometalate synzymes as catalysts for the oxidation of hydrophobic substrates in water with hydrogen peroxide

Haimov, Adina,Cohen, Hagai,Neumann, Ronny

, p. 11762 - 11763 (2004)

Combinations of alkylated polyethylenimi...

Amphiphilic Resin-Supported Rhodium-Phosphine Catalysts for C-C Bond Forming Reactions in Water

Uozumi, Yasuhiro,Nakazono, Maki

, p. 274 - 277 (2002)

Amphiphilic resin-supported rhodium-phos...

Highly sensitive and rapid detection of antibody catalysis by luminescent bacteria

Shulman, Hagit,Eberhard, Anatol,Eberhard, Carolyn,Ulitzur, Shimon,Keinan, Ehud

, p. 2353 - 2356 (2000)

A highly sensitive, inexpensive, and fac...

Selectivity of rhodium-catalyzed hydroformylation of 1-octene during batch and semi-batch reaction using trifluoromethyl-substituted ligands

Koeken, Ard C. J.,Van Vliet, Michiel C. A.,Van Den Broeke, Leo J. P.,Deelman, Berth-Jan,Keurentjes, Jos T. F.

, p. 179 - 188 (2008)

The regioselectivity of catalysts genera...

Supported Cobalt Nanoparticles for Hydroformylation Reactions

Hertrich, Maximilian Franz,Scharnagl, Florian Korbinian,Pews-Davtyan, Anahit,Kreyenschulte, Carsten Robert,Lund, Henrik,Bartling, Stephan,Jackstell, Ralf,Beller, Matthias

, p. 5534 - 5538 (2019)

Hydroformylation of olefins has been stu...

Cobalt N-heterocyclic carbene alkyl and acyl compounds: Synthesis, molecular structure and reactivity

Llewellyn, Simon A.,Green, Malcolm L. H.,Cowley, Andrew R.

, p. 4164 - 4168 (2006)

The N-heterocyclic-carbene containing co...

Stereoelectronic effects in a homologous series of bidentate cyclic phosphines. A clear correlation of hydroformylation catalyst activity with ring size

Haddow, Mairi F.,Middleton, Ann J.,Orpen, A. Guy,Pringle, Paul G.,Papp, Rainer

, p. 202 - 209 (2009)

The homologous series of diphosphines (C...

Rhodium(I) Ferrocenylcarbene Complexes: Synthesis, Structural Determination, Electrochemistry, and Application as Hydroformylation Catalyst Precursors

Ramollo, G. Kabelo,López-Gómez, María J.,Liles, David C.,Matsinha, Leah C.,Smith, Gregory S.,Bezuidenhout, Daniela I.

, p. 5745 - 5753 (2015)

New examples of the rare class of rhodiu...

Ordered mesoporous materials as solid supports for rhodium-diphosphine catalysts with remarkable hydroformylation activity

Marras, Fabrizio,Wang, Jia,Coppens, Marc-Olivier,Reek, Joost N. H.

, p. 6587 - 6589 (2010)

A rhodium-diphosphine complex based on X...

Linear amphiphilic TEMPO-grafted poly(ether sulfone) as polymeric interfacial catalyst: Synthesis, self-assembly behavior, and application

Chen, Liang,Tang, Jun,Zhang, Qi,Wang, Jianli

, p. 134 - 139 (2016)

In this study, we report the development...

Porous polymerized organocatalysts rationally synthesized from the corresponding vinyl-functionalized monomers as efficient heterogeneous catalysts

Huangfu, Ying,Sun, Qi,Pan, Shuxiang,Meng, Xiangju,Xiao, Feng-Shou

, p. 1556 - 1559 (2015)

Porous polymerized organocatalysts (PPOs...

Reaction Activity and Selectivity as a Function of Solution Ionic Strength in Oct-1-ene Hydroformylation with Sulfonated Phosphines

Ding, Hao,Hanson, Brian E.

, p. 2747 - 2748 (1994)

Salt concentration has a considerable in...

Synthesis of an Azaphosphatriptycene and Its Rhodium Carbonyl Complex

Cao, Yu,Napoline, Jonathan W.,Bacsa, John,Pollet, Pamela,Soper, Jake D.,Sadighi, Joseph P.

, p. 1868 - 1871 (2019)

A 10-aza-9-phosphatriptycene is accessib...

High pressure infrared and nuclear magnetic resonance studies of the rhodium-sulfoxantphos catalysed hydroformylation of 1-octene in ionic liquids

Silva, Silvana M.,Bronger, Raymond P. J.,Freixa, Zoraida,Dupont, Jairton,Van Leeuwen, Piet W. N. M.

, p. 1294 - 1296 (2003)

The rhodium-sulfoxantphos catalysed hydr...

β-Cyclodextrin-Modified Diphosphanes as Ligands for Supramolecular Rhodium Catalysts

Reetz, Manfred T.,Waldvogel, Siegfried R.

, p. 865 - 867 (1997)

-

Rhodium-NHC-complexes as potent catalysts in the hydroformylation of 1-octene

Bortenschlager, Martin,Schütz, Jan,Von Preysing, Denise,Nuyken, Oskar,Herrmann, Wolfgang A.,Weberskirch, Ralf

, p. 6233 - 6237 (2005)

We present an overview of eight differen...

Continuous, selective hydroformylation in supercritical carbon dioxide using an immobilised homogeneous catalyst

Meehan,Sandee,Reek,Kamer,Van Leeuwen,Poliakoff

, p. 1497 - 1498 (2000)

A continuous process for the selective h...

New phosphorus ligands for the rhodium-catalyzed isomerization/hydroformylation of internal octenes

Selent, Detlef,Hess, Dieter,Wiese, Klaus-Diether,Roettger, Dirk,Kunze, Christine,Boerner, Armin

, p. 1696 - 1698 (2001)

Going up! n-Selectivity and activity can...

Silica gel supported ferric nitrate: A convenient oxidizing reagent

Khadilkar, Bhushan,Borkar, Shobha

, p. 207 - 212 (1998)

A silica gel supported ferric nitrate wa...

Novel active dirhodium complexes for the low pressure hydroformylation reaction. Unexpected inhibiting effect of high partial pressures of hydrogen

Kalck, Philippe,Peres, Yolande,Queau, Rene,Molinier, Jacques,Escaffre, Pascale,et al.

, p. C16 - C20 (1992)

The complex tBu)2(CO)2(PPh3)2> was shown...

-

Narasaka et al.

, p. 3724 (1972)

-

N-Acetyl-N,N-dipyrid-2-yl (cyclooctadiene) rhodium (I) and iridium (I) complexes: Synthesis, X-ray structures, their use in hydroformylation and carbonyl hydrosilylation reactions and in the polymerization of diazocompounds

Bantu, Bhasker,Wurst, Klaus,Buchmeiser, Michael R.

, p. 5272 - 5278 (2007)

The synthesis of novel N-acetyl-N,N-dipy...

Continuous flow homogeneous catalysis using supercritical fluids

Webb, Paul B.,Cole-Hamilton, David J.

, p. 612 - 613 (2004)

The continuous flow hydroformylation of ...

Sol-Gel Ormosils Doped with TEMPO as Recyclable Catalysts for the Selective Oxidation of Alcohols

Ciriminna, Rosaria,Bolm, Carsten,Fey, Thomas,Pagliaro, Mario

, p. 159 - 163 (2002)

Organically modified silicas doped with ...

Mechanistic insights into a supramolecular self-assembling catalyst system: Evidence for hydrogen bonding during rhodium-catalyzed hydroformylation

Gellrich, Urs,Seiche, Wolfgang,Keller, Manfred,Breit, Bernhard

, p. 11033 - 11038 (2012)

The structural integrity and flexibility...

Hydroformylation of Oct-1-ene with Extremely High Rates using Rhodium Catalysts containing Bulky Phosphites

Rooy, Annemiek van,Orij, Edwin N.,Kamer, Paul C. J.,Aardweg, Fred van den,Leeuven, Piet W. N. M. van

, p. 1096 - 1097 (1991)

A rhodium complex containing tris(o-tert...

Preparation of Polymer Supported Phosphine Ligands by Metal Catalyzed Living Radical Copolymerization and Their Application to Hydroformylation Catalysis

Cardozo, Andres F.,Manoury, Eric,Julcour, Carine,Blanco, Jean-Francois,Delmas, Henri,Gayet, Florence,Poli, Rinaldo

, p. 1161 - 1169 (2013)

A series of well-defined polystyrene-sup...

Room temperature ambient pressure (RTAP)-hydroformylation in water using a self-assembling ligand

Straub, Alexander T.,Otto, Marina,Usui, Ippei,Breit, Bernhard

, p. 2071 - 2075 (2013)

We herein demonstrate a hydroformylation...

Functionalized-1,3,4-oxadiazole ligands for the ruthenium-catalyzed Lemieux-Johnson type oxidation of olefins and alkynes in water

Hkiri, Shaima,Touil, Soufiane,Samarat, Ali,Sémeril, David

, (2021/11/30)

Three arene-ruthenium(II) complexes bear...

Spongy titanosilicate promotes the catalytic performance and reusability of WO3 in oxidative cleavage of methyl oleate

Huang, Zuoxin,Lin, Min,Peng, Xinxin,Shu, Xingtian,Xia, Changjiu,Xin, Shihao,Zhang, Yao,Zheng, Aiguo,Zhu, Bin

, p. 5135 - 5144 (2022/02/25)

A tungsten containing catalyst catalyzed...

Synthesis of α,β-unsaturated epoxy ketones utilizing a bifunctional sulfonium/phosphonium ylide

Eskandari, Roozbeh,Hess, Jeremy P.,Tochtrop, Gregory P.

supporting information, p. 7136 - 7139 (2021/07/28)

Herein, a new protocol for rapid synthes...

Micellar Catalysis for Sustainable Hydroformylation

Calamante, Massimo,Dei, Filippo,Maramai, Samuele,Migliorini, Francesca,Petricci, Elena

, p. 2794 - 2806 (2021/05/03)

It is here reported a fully sustainable ...

124-19-6 Process route

oct-1-ene
111-66-0,25068-25-1

oct-1-ene

carbon monoxide
201230-82-2

carbon monoxide

nonan-1-al
124-19-6

nonan-1-al

trans-2-Octene
13389-42-9

trans-2-Octene

2-methyl-1-octanal
49642-49-1,55352-42-6,72598-55-1,7786-29-0

2-methyl-1-octanal

Conditions
Conditions Yield
With acetylacetonatodicarbonylrhodium(l); tris(m-pyridyl)phosphane-[N-zinc(tetraphenylporphyrin)]3; hydrogen; at 25 ℃; Further Variations:; Reagents; Product distribution;
With 1,4-diaza-bicyclo[2.2.2]octane; tris(zinc(II) porphyrin)phosphite derivative; hydrogen; acetylacetonatodicarbonylrhodium(l); In toluene; at 30 ℃; for 17h; under 15001.2 Torr; Further Variations:; Temperatures; Reagents; Product distribution;
With hydrogen; tris(para-pyridyl)phosphine; acetylacetonatodicarbonylrhodium(l); In toluene; at 25 ℃; for 65h; under 15001.2 Torr; Further Variations:; Reagents; Product distribution;
With phosphine ligand; hydrogen; N-ethyl-N,N-diisopropylamine; carbonylhydridetris(triphenylphosphine)rhodium(I); In toluene; at 25 ℃; for 43h; under 15001.2 Torr; Further Variations:; Catalysts; Temperatures; Reagents; Product distribution;
oct-1-ene
111-66-0,25068-25-1

oct-1-ene

carbon monoxide
201230-82-2

carbon monoxide

nonan-1-al
124-19-6

nonan-1-al

(E)-3-octene
14919-01-8

(E)-3-octene

trans-2-Octene
13389-42-9

trans-2-Octene

2-methyl-1-octanal
49642-49-1,55352-42-6,72598-55-1,7786-29-0

2-methyl-1-octanal

Conditions
Conditions Yield
With hydrogen; N-ethyl-N,N-diisopropylamine; acetylacetonatodicarbonylrhodium(l); In decane; toluene; at 80 ℃; for 1h; under 15001.5 Torr; Further byproducts.;
26%

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