gamma-hexalactone

Available forms:colourless to pale yellow liquid with a herbaceous, sweet odour

pd_proNo:526343-a58ce6a7-a302-484d-a86b-11f9a4707790

pd_productuse:

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Detailed introduction

Buy high quality and low price gamma-hexalactone 695-06-7 now

  • Molecular Formula:C6H10O2
  • Molecular Weight:114.144
  • Appearance/Colour:colourless to pale yellow liquid with a herbaceous, sweet odour 
  • Vapor Pressure:0.152mmHg at 25°C 
  • Melting Point:-18 °C 
  • Refractive Index:n20/D 1.439(lit.)  
  • Boiling Point:214.904 °C at 760 mmHg 
  • Flash Point:79.338 °C 
  • PSA:26.30000 
  • Density:1.003 g/cm3 
  • LogP:1.10200 

4-Hexanolide(Cas 695-06-7) Usage

Preparation

By reduction of sorbic acid using Zn, Sn or SnCl2 and concentrated HCl in acetic acid solution at 85°C; from ethylene oxide and sodio-malonic ester; also from propyl alcohol and methylacrylate in the presence of di-tert-butyl peroxide

Synthesis Reference(s)

Tetrahedron Letters, 28, p. 2111, 1987 DOI: 10.1016/S0040-4039(00)96056-8

Definition

4-Hexanolide is a gamma-lactone that is oxolan-2-one substituted by an ethyl group at position 5.

Aroma threshold values

Detection: 1.6 ppm

Taste threshold values

Taste characteristics at 75 ppm: sweet, creamy, vanilla-like with green lactonic powdery nuances

General Description

γ-Hexalactone is a volatile flavoring compound largely present in food and beverage products, fruits, vegetables, etc.

InChI:InChI=1/C6H10O2/c1-2-5-3-4-6(7)8-5/h5H,2-4H2,1H3/t5-/m1/s1

695-06-7 Relevant articles

SYNTHESIS OF γ-LACTONES BY THE HYDROBORYLATION AND OXIDATION OF HOMOALLYLIC ALCOHOLS

Hao, Nguyen Cong,Mavrov, M. V.,Chrelashvili, Z. G.,Serebryakov, E. P.

, p. 1042 - 1044 (1988)

-

Photoinduced Lactonisation. A Useful but Mechanistically Complex Single Electron Transfer Process

Gassman, Paul G.,Bottorff, Kyle J.

, p. 7547 - 7548 (1987)

-

Calcium(II)- And Triflimide-Catalyzed Intramolecular Hydroacyloxylation of Unactivated Alkenes in Hexafluoroisopropanol

Qi, Chenxiao,Yang, Shengwen,Gandon, Vincent,Leb?uf, David

supporting information, p. 7405 - 7409 (2019/10/02)

We report an efficient intramolecular hy...

W(OTf)6-Catalyzed Synthesis of Γ-Lactones by Ring Contraction of Macrolides or Ring Closing of Terminal Hydroxyfatty Acids in Ionic Liquid

Xie, Zhong-Yu,Deng, Jin,Fu, Yao

, p. 2332 - 2339 (2018/07/31)

γ-Lactones are an important class of fin...

Preparation method of gamma-caprolactone

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Paragraph 0033-0035; 0042-0044; 0048-0050; 0054-0063, (2017/08/28)

The invention provides a preparation met...

1H-pyrrole-2,4-dicarbonyl-derivatives and their use as flavoring agents

-

, (2015/03/03)

The present invention primarily relates ...

695-06-7 Process route

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hexahydro-2H-oxepin-2-one

hexan-4-olide
695-06-7

hexan-4-olide

Conditions
Conditions Yield
In dichloromethane; at -30 ℃; for 2h; Yield given. Yields of byproduct given;
hexan-4-olide
695-06-7

hexan-4-olide

hex-3-enoic acid
4219-24-3

hex-3-enoic acid

Conditions
Conditions Yield
bei der Destillation;

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