2-Acetylthiazole

Available forms:white to light yellow crystal powder

pd_proNo:373477-f7a1e5be-08ae-43f1-9c01-cbd96671091a

pd_productuse:

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Detailed introduction

Quality Factory Sells Top Purity 99% 2-Acetylthiazole 24295-03-2 with Safe Delivery

  • Molecular Formula:C5H5NOS
  • Molecular Weight:127.167
  • Appearance/Colour:white to light yellow crystal powder 
  • Vapor Pressure:0.173mmHg at 25°C 
  • Melting Point:65.5 °C 
  • Refractive Index:n20/D 1.548(lit.)  
  • Boiling Point:212.509 °C at 760 mmHg 
  • PKA:0.05±0.10(Predicted) 
  • Flash Point:82.323 °C 
  • PSA:58.20000 
  • Density:1.227 g/cm3 
  • LogP:1.34570 

2-Acetylthiazole(Cas 24295-03-2) Usage

Preparation

2-Acetylthiazole is formed by oxidation of the corresponding carbinol using dichromate.

Synthesis Reference(s)

The Journal of Organic Chemistry, 53, p. 1748, 1988 DOI: 10.1021/jo00243a029

Purification Methods

Check NMR spectrum; if it is not too bad, distil it through an efficient column in a vacuum. The oxime sublimes at 140-145o, m 159o, and when crystallised from H2O has m 163-165.5o. [Erlenmeyer et al. Helv Chim Acta 31 1142 1948, Waisvisz et al. J Am Chem Soc 79 4524 1957, Menasseé et al. Helv Chim Acta 40 554 1957, Beilstein 27 IV 2617.]

Aroma threshold values

Detection at 4 ppb

Taste threshold values

Taste characteristics at 30 ppm: corn chip with slightly musty background

General Description

2-Acetylthiazole is a volatile flavoring substance generally formed by the Maillard reaction between an amino acid and carbonyl compounds. It is reported to occur in canned sweet corn products, cooked pine mushroom, cooked asparagus and roasted beef.

InChI:InChI=1/C5H5NOS/c1-4(7)5-6-2-3-8-5/h2-3H,1H3

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24295-03-2 Process route

L-Cysteine
52-90-4

L-Cysteine

[1-<sup>13</sup>C]ascorbic acid
178101-88-7

[1-13C]ascorbic acid

2,5-dihydro-thiophene
1708-32-3

2,5-dihydro-thiophene

thiophene
188290-36-0,8014-23-1,25233-34-5

thiophene

2-Methylthiophene
554-14-3

2-Methylthiophene

4,5-Dimethylthiazole
3581-91-7

4,5-Dimethylthiazole

4,5-Dihydro-2-methylthiophen-3-(2H)-on
74015-70-6,13679-85-1

4,5-Dihydro-2-methylthiophen-3-(2H)-on

2,4,5-trimethylthiazole
13623-11-5

2,4,5-trimethylthiazole

2-Acetylthiophene
88-15-3,97511-16-5

2-Acetylthiophene

2-Acetylthiazole
24295-03-2,260998-74-1

2-Acetylthiazole

2-acetyl-3-methylthiophene
13679-72-6

2-acetyl-3-methylthiophene

3-(vinylthio)thiophene
867253-51-8

3-(vinylthio)thiophene

Conditions
Conditions Yield
at 140 ℃; for 2h; pH=8; aq. phosphate buffer; Sealed vessel;
L-Cysteine
52-90-4

L-Cysteine

ascorbic acid
50-81-7,98966-42-8

ascorbic acid

2,5-dihydro-thiophene
1708-32-3

2,5-dihydro-thiophene

thiophene
188290-36-0,8014-23-1,25233-34-5

thiophene

2-Methylthiophene
554-14-3

2-Methylthiophene

4,5-Dimethylthiazole
3581-91-7

4,5-Dimethylthiazole

4,5-Dihydro-2-methylthiophen-3-(2H)-on
74015-70-6,13679-85-1

4,5-Dihydro-2-methylthiophen-3-(2H)-on

2,4,5-trimethylthiazole
13623-11-5

2,4,5-trimethylthiazole

2-Acetylthiophene
88-15-3,97511-16-5

2-Acetylthiophene

2-Acetylthiazole
24295-03-2,260998-74-1

2-Acetylthiazole

2-acetyl-3-methylthiophene
13679-72-6

2-acetyl-3-methylthiophene

3-(vinylthio)thiophene
867253-51-8

3-(vinylthio)thiophene

Conditions
Conditions Yield
at 140 ℃; for 2h; pH=8; aq. phosphate buffer; Sealed vessel;

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