

Available forms:colorless to amber liquid with an extremely foul and persistent odor
pd_proNo:542836-4c9e5af8-cfd6-4551-b336-5a004c590e18
pd_productuse:
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Preparation |
By transamination and decarboxylation of various amino acids; by oxidation of the alcohol |
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Synthesis Reference(s) |
Journal of the American Chemical Society, 70, p. 1450, 1948 DOI: 10.1021/ja01184a044 |
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Air & Water Reactions |
Slightly soluble in water. |
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Reactivity Profile |
Organosulfides, such as 3-(Methylthio)propionaldehyde, are incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. Many of these compounds may liberate hydrogen sulfide upon decomposition or reaction with an acid. |
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Health Hazard |
Highly toxic, may be fatal if inhaled, swallowed or absorbed through skin. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. |
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Fire Hazard |
Combustible material: may burn but does not ignite readily. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form. |
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Flammability and Explosibility |
Notclassified |
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Biochem/physiol Actions |
Taste at 0.5-1ppm |
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Safety Profile |
Moderately toxic by ingestion. When heated to decomposition it emits toxic vapors of SOx. |
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Aroma threshold values |
Aroma characteristics at 0.1%: vegetable oil, creamy tomato, potato skin and French fry, yeasty, bready, limburger cheese with a savory meaty brothy nuance |
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Taste threshold values |
Taste characteristics at 5 ppb to 5 ppm: potato, musty, tomato, mold ripened cheeses, onion, beefy brothy, egg, seafood and vegetative nuances. |
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General Description |
A colorless to amber liquid with an extremely foul and persistent odor. Slightly soluble in water and denser than water. Contact may slightly irritate skin, eyes and mucous membranes. Moderately toxic. Used as a food additive. |
InChI:InChI=1/C4H8OS/c1-4(3-5)6-2/h3-4H,1-2H3
The generation of pyrazines in a binary ...
Provided by the present disclosure are a...
The oxidation of alcohols to aldehydes o...
We report here new copper(I)-Schiff base...
DL-methionine
3-methylthio-1-propanamine
3-(methylsulfenyl)propanal
methionine S-oxide
2-aminobutanoic acid
| Conditions | Yield |
|---|---|
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With
water; dinitrogen monoxide;
Mechanism;
Quantum yield;
γ-irradiation;
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3-methanesulfinyl-propionaldehyde
3-(methylsulfenyl)propanal
| Conditions | Yield |
|---|---|
|
With
N,N,N’,N’-tetrabromobenzene-1,3-disulfonamide; triphenylphosphine;
In
dichloromethane;
at 20 ℃;
for 0.0166667h;
|
90% |
3-(methylthio)propionitrile
1,1-diethoxy-3-methylsulfanyl-propane
methylthiol
triethylamine
isonicotinic acid-(3-methylsulfanyl-propylidenehydrazide)
2-hydroxy-4-(methylthio)butyronitrile
5-[2-(methylthio)ethyl]imidazolidine-2,4-dione
2-[(aminocarbonyl)amino]-4-(methylthio)butanoamide
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