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pd_proNo:486630-91c9a88f-c2d6-4a0d-89b5-9faea95a7b4c
pd_productuse:
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General Description |
Menthyl acetate (MA), a monoterpene is one of the main constituent of the peppermint essential oil obtained from the leaves of Mentha piperita. It has been reported to show ambulation-promoting effect in mice. Its fumigant and repellent activity has been evaluated on first-instar nymphs of the bloodsucking bug Rhodnius prolixus. The decomposition of MA in an atmospheric flow reactor and a low-pressure flat flame has been investigated by molecular-beam mass spectrometry (MBMS). |
InChI:InChI=1/C12H22O2/c1-8(2)11-6-5-9(3)7-12(11)14-10(4)13/h8-9,11-12H,5-7H2,1-4H3/t9-,11+,12-/m0/s1
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The invention relates to a method for pr...
Monoterpenic esters are very important f...
Abstract: Enzymatic transesterification ...
menthol
acetic anhydride
2-isopropyl-5-methylcyclohexyl acetate
| Conditions | Yield |
|---|---|
|
With
lithium perchlorate;
at 25 ℃;
for 22h;
|
98% |
|
With
silica gel;
for 0.05h;
Microwave irradiation;
neat (no solvent);
|
98% |
|
With
SBA-15-Ph-Pr-SO3H;
at 20 ℃;
for 0.416667h;
|
98% |
|
4-N,N-dimethylaminopyridinium saccharinate;
at 25 ℃;
Product distribution / selectivity;
|
98% |
|
With
C12H8N2*2CH4O3S;
at 30 ℃;
for 2h;
|
98% |
|
With
poly(N,N'-dibromo-N-ethylnaphthyl-2,7-sulfonamide);
In
neat (no solvent);
at 20 ℃;
for 0.5h;
|
97% |
|
With
poly(4-vinylpyridine) supported copper(II) oxide nanoparticles;
In
neat (no solvent);
at 20 ℃;
for 0.05h;
chemoselective reaction;
|
95% |
|
With
lanthanum(III) nitrate;
at 20 ℃;
for 0.25h;
|
94% |
|
With
1-butyl-3-methylimidazolium tetrachloridoferrate(III);
at 20 ℃;
for 1.16667h;
Ionic liquid;
|
94% |
|
With
rice husk ash;
at 80 ℃;
for 1h;
Green chemistry;
|
93% |
|
With
20CuO-ZnO nanocatalyst;
In
dichloromethane;
at 20 ℃;
for 1h;
Green chemistry;
|
89% |
|
With
benzyltriphenylphosphonium tribromide;
In
chloroform;
for 0.216667h;
Reflux;
|
87% |
|
With
camphor-10-sulfonic acid; Graphite;
In
neat (no solvent);
at 20 ℃;
for 0.5h;
|
82% |
|
With
1H-imidazole;
at 20 ℃;
for 24h;
Green chemistry;
|
75% |
|
magnesium bromide;
In
dichloromethane;
at 20 ℃;
for 3h;
|
72% |
|
With
pyridine;
In
dichloromethane;
|
|
|
With
bismuth(lll) trifluoromethanesulfonate;
at 0 ℃;
for 1.5h;
|
97 % Chromat. |
|
With
sulfonated ordered mesoporous carbon (CMK-5-SO3H);
In
neat (no solvent);
at 20 ℃;
for 0.166667h;
Green chemistry;
|
98 %Chromat. |
|
With
cesium 12-tungstophosphate;
at 20 ℃;
for 0.5h;
Time;
Catalytic behavior;
Green chemistry;
|
|
|
With
immobilized enzyme Novozym 435?;
at 150 ℃;
Enzymatic reaction;
|
vinyl acetate
menthol
2-isopropyl-5-methylcyclohexyl acetate
| Conditions | Yield |
|---|---|
|
iodine;
at 20 ℃;
for 4.5h;
|
94% |
|
With
2,2'-(phenylimino)bis[ethanol]; diethylzinc;
In
hexane; toluene;
at 20 ℃;
for 24h;
|
91% |
|
With
pseudomonas fuorescens lipase immobilized on multiwall carbon nano-tubes;
at 50 ℃;
for 12h;
Green chemistry;
|
44% |
acetic anhydride
menthol
[1-α]-5-methyl-2-[1-methylethyl]-cyclohexanol
vinyl acetate
menthol
(-)-menthol
D-menthyl acetate
(1S,2R,5S)-(+)-menthol
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