Detailed introduction

Buy reliable Quality Methyl heptanoate 106-73-0 raw material with Honest Price

Molecular Formula:C8H16 O2
Molecular Weight:144.214
Appearance/Colour:clear colorless liquid
Vapor Pressure:1.43mmHg at 25°C
Melting Point:-56°C
Refractive Index:n20/D 1.411(lit.)
Boiling Point:172-173ºC(lit.)
Flash Point:52 ºC
PSA：26.30000
Density:0.87
LogP:2.12980

Methyl heptanoate(Cas 106-73-0) Usage

Preparation	By treating heptanoic acid with methyl alcohol in the presence of HCl or H2SO4
Synthesis Reference(s)	Canadian Journal of Chemistry, 52, p. 3651, 1974 DOI: 10.1139/v74-546Journal of the American Chemical Society, 95, p. 1296, 1973 DOI: 10.1021/ja00785a047Tetrahedron Letters, 29, p. 3833, 1988 DOI: 10.1016/S0040-4039(00)82127-9
Aroma threshold values	Detection: 4 ppb
Taste threshold values	Taste characteristics at 35 ppm: sweet fruity and green
General Description	Methyl heptanoate has been identified in pineapple, Hardy kiwifruit and salak fruit.

InChI:InChI=1/C8H16O2/c1-3-4-5-6-7-8(9)10-2/h3-7H2,1-2H3

106-73-0 Relevant articles

-

Cobern,D. et al.

, p. 1897 - 1902 (1966)

Ruthenium complex immobilized on supported ionic-liquid-phase (SILP) for alkoxycarbonylation of olefins with CO2

Xia, Shi-Ping,Ding, Guang-Rong,Zhang, Rui,Han, Li-Jun,Xu, Bao-Hua,Zhang, Suo-Jiang

, p. 3073 - 3080 (2021)

In this study, the heterogeneously catal...

-

Bertelo,Schwartz

, p. 228 (1975)

Tuning the regioselectivity of (benzimidazolylmethyl)amine palladium(II) complexes in the methoxycarbonylation of hexenes and octenes

Tshabalala, Thandeka A.,Ojwach, Stephen O.

, p. 339 - 346 (2018)

Reactions of N-(1H-benzoimidazol-2-ylmet...

-

Urry,Huyser

, p. 4876 (1953)

Efficient and selective oxidation of aldehydes with dioxygen catalysed by vanadium-containing heteropolyanions

El Amrani, Ikram,Atlamsani, Ahmed,Dakkach, Mohamed,Rodríguez, Montserrat,Romero, Isabel,Amthiou, Souad

, p. 888 - 895 (2017)

The heteropolyacids “H3+n[PMo12–nVnO40]·...

VITAMIN B12 PHOTOELECTROCATALYSED (B12/PEC) SYNTHESIS OF 2-AMINOESTERS

Orlinski, Ryszard,Stankiewicz, Tomasz

, p. 1601 - 1602 (1988)

Vit.B12 photoelectrocatalysed addition o...

Platinum Complex Catalyzed Carbonylation of Organic Iodides: Effective Carbonylation of Organic Iodides Having β-Hydrogens on Saturated sp3 Carbons

Takeuchi, Ryo,Tsuji, Yasushi,Fujita, Masayuki,Kondo, Teruyuki,Watanabe, Yoshihisa

, p. 1831 - 1836 (1989)

Dichlorobis(triphenylphosphine)platinum(...

Isolation of the β-galactosphingolipid coniferoside using a tumor cell proteome reverse affinity protocol

La Clair, James J.,Rodriguez, Abimael D.

, p. 6645 - 6653 (2011)

New approaches are vital to the developm...

Methoxycarbonylation of olefins catalysed by homogeneous palladium(II) complexes of (phenoxy)imine ligands bearing alkoxy silane groups

Akiri, Saphan O.,Ojwach, Stephen O.

, p. 236 - 243 (2019)

The Schiff base compounds 2-phenyl-2-((3...

FURTHER STUDIES ON THE UTILITY OF SODIUM HYPOCHLORITE IN ORGANIC SYNTHESIS. SELECTIVE OXIDATION OF DIOLS AND DIRECT CONVERSION OF ALDEHYDES TO ESTERS

Stevens, Robert V.,Chapman, Kevin T.,Stubbs, Cheryl A.,Tam, Weyton W.,Albizati, Kim F.

, p. 4647 - 4650 (1982)

Sodium hypochlorite in acetic acid solut...

Pd-catalysed formation of ester products from cascade reaction of 5-hydroxymethylfurfural with 1-hexene

Garcia-Suarez, Eduardo J.,Paolicchi, Dario,Li, Hu,He, Jian,Yang, Song,Riisager, Anders,Saravanamurugan, Shunmugavel

, p. 170 - 174 (2019)

A cascade reaction involving decarbonyla...

-

Doering,Knox

, p. 4947,4950 (1956)

Palladium(II) complexes of (pyridyl)imine ligands as catalysts for the methoxycarbonylation of olefins

Zulu, Zethu,Nyamato, George S.,Tshabalala, Thandeka A.,Ojwach, Stephen O.

, (2020)

Reactions of 2-methoxy-N-((pyridin-2-yl)...

Toward the development of efficient and stable Pd-catalysts for the methoxycarbonylation of medium chain alkenes

Bredenkamp, Tyler,Holzapfel, Cedric

, p. 421 - 427 (2016)

Methoxycarbonylation provides a one-step...

PHOTOCHEMICAL CARBONYLATION OF ALKYL IODIDES IN THE PRESENCE OF VARIOUS METAL CARBONYLS

Kondo, Teruyuki,Tsuji, Yasushi,Watanabe, Yoshihisa

, p. 3833 - 3836 (1988)

Various transition metal complexes inclu...

Electron-Transfer-Photosensitized Conjugate Alkylation

Fagnoni, Maurizio,Mella, Mariella,Albini, Angelo

, p. 4026 - 4033 (1998)

Photoinduced electron transfer (PET) fro...

Electron-transfer Reductions by Active Aldehydes catalysed by Thiazolium Salt in the Presence of Triethylamine

Inoue, Hiroo,Higashiura, Kunihiko

, p. 549 - 550 (1980)

3-Benzylthiazolium salts, in methanol co...

Ruthenium catalysed oxidation without CCl4 of oleic acid, other monoenic fatty acids and alkenes

Zimmermann, Fran?ois,Meux, Eric,Mieloszynski, Jean-Luc,Lecuire, Jean-Marie,Oget, Nicolas

, p. 3201 - 3203 (2005)

Ruthenium catalysed oxidation of alkenes...

Flexible polyurethanes, renewable fuels, and flavorings from a microalgae oil waste stream

Burkart, Michael D.,Griffin, Graham,Mayfield, Stephen P.,Neelakantan, Nitin,Phung Hai, Thien An,Pomeroy, Robert,Sherman, Suryendra D.,Tessman, Marissa

, p. 3088 - 3094 (2020)

Renewable polymers have become an import...

-

Kozikowski,A.P.,Ames,A.

, p. 2735 - 2737 (1978)

Photo-, electro-, and thermal carbonylation of alkyl iodides in the presence of Group 7 and 8-10 metal carbonyl catalysts

Kondo, Teruyuki,Sone, Yoshitsugu,Tsuji, Yasushi,Watanabe, Yoshihisa

, p. 163 - 174 (1994)

Various transition-metal complexes inclu...

Electrochemical esterification via oxidative coupling of aldehydes and alcohols

Smeyne, Dylan,Verboom, Katherine,Bryan, Maria,LoBue, James,Shaikh, Abid

supporting information, (2021/03/26)

An electrolytic method for the direct ox...

Liquid-phase oxidation of olefins with rare hydronium ion salt of dinuclear dioxido-vanadium(V) complexes and comparative catalytic studies with analogous copper complexes

Maurya, Abhishek,Haldar, Chanchal

, (2021/02/26)

Homogeneous liquid-phase oxidation of a ...

Structural studies and applications of water soluble (phenoxy)imine palladium(II) complexes as catalysts in biphasic methoxycarbonylation of 1-hexene

Akiri, Saphan O.,Ojwach, Stephen O.

, (2021/04/27)

Reactions of the ligands; sodium 4?hydro...

Sterically hindered (pyridyl)benzamidine palladium(II) complexes: Syntheses, structural studies, and applications as catalysts in the methoxycarbonylation of olefins

Akiri, Saphan O.,Ojwach, Stephen O.

, (2021/09/09)

Reactions of ligands (E)-N′-(2,6-diisopr...

106-73-0 Process route

: 67-56-1
methanol

: 111-71-7
heptanal

: 40416-74-8
1-Hydroperoxy-1-methoxypentan

: 10032-05-0
1,1-dimethoxyheptane

: 624-24-8
methyl valerate

: 106-73-0
methyl heptanoate

: 26450-58-8
1,1-dimethoxy-pentane

Conditions

Conditions	Yield
With hydrogenchloride; Mechanism; Product distribution; -78 deg C to r.t.;	21 % Chromat. 26 % Chromat. 21 % Chromat. 27 % Chromat.

: 67-56-1
methanol

: 343217-90-3
3,5-dihexyl-1,2,4-trioxolan

: 10032-05-0
1,1-dimethoxyheptane

: 106-73-0
methyl heptanoate

Conditions

Conditions	Yield
With chlorosulfonic acid; dihydrogen peroxide; at 20 ℃; for 100h;	27% 33%

106-73-0 Upstream products

6832-16-2
methyl diazoacetate
109-66-0
pentane
67-56-1
methanol
628-71-7
1-Heptyne

106-73-0 Downstream products

5445-31-8
2-methyl-nonan-3-one
624-16-8
decan-4-one
54340-91-9
methyl rac-2-hydroxyheptanoate
22371-32-0
heptanoic acid hydrazide