What is the Anisyl acetate?

Anisyl acetate is clear colourless to pale yellowish liquid, while it's Molecular Formula is C10H12O3. clear colourless to pale yellowish liquid Perfumery, flavoring.

What is the CAS number for Anisyl acetate?

The CAS number of Anisyl acetate is 104-21-2.

What is Anisyl acetate (104-21-2) used for?

Anisyl acetate, also known as 4-methoxyphenyl acetate, is a naturally occurring organic compound that is widely used in the perfumery and flavor industries. It is a clear, colorless to pale yellowish liquid with a floral, fruit-like odor and a slight pungent, sweet taste. Anisyl acetate is characterized by its fruity, floral, vanilla, coconut, honey, cocoa, anise, and licorice taste at a threshold value of 30 ppm. It has been reported to be found in vanilla and currants.InChI:InChI=1/C10H12O3/c1-3-7-6-8(13-2)4-5-9(7)10(11)12/h4-6H,3H2,1-2H3,(H,11,12)/p-1

What is the Anisyl acetate?

Anisyl acetate is clear colourless to pale yellowish liquid, while it's Molecular Formula is C10H12O3. clear colourless to pale yellowish liquid Perfumery, flavoring.

What is the CAS number for Anisyl acetate?

The CAS number of Anisyl acetate is 104-21-2.

What is Anisyl acetate (104-21-2) used for?

Anisyl acetate, also known as 4-methoxyphenyl acetate, is a naturally occurring organic compound that is widely used in the perfumery and flavor industries. It is a clear, colorless to pale yellowish liquid with a floral, fruit-like odor and a slight pungent, sweet taste. Anisyl acetate is characterized by its fruity, floral, vanilla, coconut, honey, cocoa, anise, and licorice taste at a threshold value of 30 ppm. It has been reported to be found in vanilla and currants.InChI:InChI=1/C10H12O3/c1-3-7-6-8(13-2)4-5-9(7)10(11)12/h4-6H,3H2,1-2H3,(H,11,12)/p-1

Detailed introduction

High quality purity >99% Anisyl Acetate 104-21-2 for sale

Molecular Formula:C10H12O3
Molecular Weight:180.203
Appearance/Colour:clear colourless to pale yellowish liquid
Vapor Pressure:0.000846mmHg at 25°C
Melting Point:84oC
Refractive Index:n20/D 1.513(lit.)
Boiling Point:251.376 °C at 760 mmHg
Flash Point:98.919 °C
PSA：35.53000
Density:1.084 g/cm³
LogP:1.75830

Anisyl acetate(Cas 104-21-2) Usage

Preparation	May be prepared by the reaction of anisic alcohol with acetic anhydride
Synthesis Reference(s)	The Journal of Organic Chemistry, 40, p. 3647, 1975 DOI: 10.1021/jo00913a006
Flammability and Explosibility	Nonflammable
Biochem/physiol Actions	Taste at 30 ppm
Safety Profile	Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
Taste threshold values	Taste characteristics at 30 ppm: fruity, floral, vanilla, coconut, honey, cocoa, anise and licorice

InChI:InChI=1/C10H12O3/c1-3-7-6-8(13-2)4-5-9(7)10(11)12/h4-6H,3H2,1-2H3,(H,11,12)/p-1

104-21-2 Relevant articles

-

Cavill,Solomon

, p. 3943,3946 (1954)

Microwave-assisted NiCl2 promoted acylation of alcohols

Constantinou-Kokotou, Violetta,Peristeraki, Anna

, p. 4227 - 4232 (2004)

A microwave oven acylation of alcohols b...

The Mechanism of Enzymatic and Biomimetic Oxidations of Aromatic Sulfides and Sulfoxides

Baciocchi, Enrico,Lanzalunga, Osvaldo,Marconi, Francesco

, p. 9771 - 9774 (1994)

Biomimetic and enzymatic oxidations of b...

Synthesis, Characterisation, and Determination of Physical Properties of New Two-Protonic Acid Ionic Liquid and its Catalytic Application in the Esterification

Shahnavaz, Zohreh,Zaharani, Lia,Khaligh, Nader Ghaffari,Mihankhah, Taraneh,Johan, Mohd Rafie

, p. 165 - 172 (2021)

A new ionic liquid was synthesised, and ...

Acetylation of alcohols and phenols under solvent-free conditions using copper zirconium phosphate

Hajipour, Abdol R.,Karimi, Hirbod

, p. 1982 - 1989 (2014)

Copper zirconium phosphate nanoparticles...

Synthesis and characterization of MCM-41@XA@Ni(II) as versatile and heterogeneous catalyst for efficient oxidation of sulfides and acetylation of alcohols under solvent-free conditions

Nazarzadeh, Somayeh,Ghorbani-Choghamarani, Arash,Tahanpesar, Elham

, p. 649 - 659 (2018)

Herein, Ni(II) immobilized on modified m...

Side-Chain Oxidation of α-Substituted 4-Methoxytoluenes by Potassium 12-Tungstocobalt(III)ate. The Effect of α-Substituents on the Formation and Deprotonation of the Intermediate Cation Radicals

Baciocchi, Enrico,Bietti, Massimo,Mattioli, Mario

, p. 7106 - 7110 (1993)

A kinetic study of the side-chain oxidat...

CuSO4 as a mild, green, and efficient catalyst for the one-pot conversion of THP ethers to acetates

Asadolah, Karim,Heravi, Majid M.

, p. 867 - 869 (2007)

An efficient direct conversion of THP et...

AUTOCATALYTIC SOLVOLITIC DEMERCURATION OF 4-METHOXYBENZYLMERCURIC CHLORIDE

Butin, K. P.,Magdesieva, T. V.,Voskoboinikov, A. Z.,Reutov, O. A.

, (1987)

Molecular iodine in ionic liquid: A green catalytic system for esterification and transesterification

Ren, Yiming,Cai, Chun

, p. 1670 - 1676 (2010)

Esterification of carboxylic acids and t...

Photoredox-Catalyzed Benzylic Esterification via Radical-Polar Crossover

Maeda, Bumpei,Sakakibara, Yota,Murakami, Kei,Itami, Kenichiro

, p. 5113 - 5117 (2021)

Photoredox-catalyzed C-O bond formation ...

Transprotection of silyl ethers of nucleosides in FeCl3 based ionic liquids

Harjani, Jitendra R.,Nara, Susheel J.,Salunkhe, Manikrao M.,Sanghvi, Yogesh S.

, p. 819 - 822 (2005)

Ionic liquid mediated deprotection of te...

Benzyl Acetates by Acetoxylation of Methylbenzenes using Peroxydisulfate as Oxidizing Agent

Belli, Aldo,Giordano, Claudio,Citterio, Attilio

, p. 477 - 479 (1980)

Iodine as an extremely powerful catalyst for the acetylation of alcohols under solvent-free conditions

Phukan, Prodeep

, p. 4785 - 4787 (2004)

Iodine was found to promote quantitative...

Vitamin B1 supported on silica-encapsulated γ-Fe 2O3 nanoparticles: Design, characterization and application as a greener biocatalyst for highly efficient acylation

Azizi, Kobra,Heydari, Akbar

, p. 8812 - 8816 (2014)

A new magnetic catalyst was synthesized ...

An approach to heterodiarylmethanes via sp2-sp3 Suzuki-Miyaura cross-coupling

Stewart, Gavin W.,Maligres, Peter E.,Baxter, Carl A.,Junker, Ellyn M.,Krska, Shane W.,Scott, Jeremy P.

, p. 3701 - 3706 (2016)

The synthesis of a range of structurally...

Green bioprocesses in sponge-like ionic liquids

Lozano, Pedro,Bernal, Juana M.,Gómez, Celia,García-Verdugo, Eduardo,Isabel Burguete,Sánchez, Gregorio,Vaultier, Michel,Luis, Santiago V.

, p. 54 - 59 (2015)

Abstract Ionic liquids (ILs) are a new c...

Acetylation of alcohols and phenols under solvent-free conditions using iron zirconium phosphate

Hajipour, Abdol R.,Karimi, Hirbod,Masti, Amir

, p. 595 - 602 (2015)

Iron zirconium phosphate (ZPFe) nanopart...

Potassium fluoride assisted selective acetylation of alcohols with acetic acid

Bosco, J. W. John,Raju, B. Rama,Saikia, Anil K.

, p. 2849 - 2855 (2004)

Potassium fluoride promotes the acetylat...

Molecular iodine catalyzed selective acetylation of alcohols with vinyl acetate

Bosco, J.W. John,Agrahari, Aditya,Saikia, Anil K.

, p. 4065 - 4068 (2006)

Molecular iodine is found to catalyze th...

Hierarchically porous Br?nsted acidic ionic liquid functionalized nitrogen-doped carbons for pyrolysis biofuel upgrading via esterification of acetic acid with high boiling point alcohols

Zhang, Qingqing,Zhang, Chaoyue,Sun, Yingnan,Guo, Yihang,Song, Daiyu

, p. 10 - 24 (2019)

Br?nsted acidic ionic liquid (BAIL) func...

Trimethylsilylation of alcohols and phenols, and direct acetylation of silyl ethers catalyzed by Fe(ClO4)3.6H2O

Oskooie, Hossein A.,Heravi, Majid M.,Tehrani, Maryam H.,Behbahani, Farahnaz K.,Heravi, Omid M.

, p. 1729 - 1737 (2009)

In this article, a mild and efficient pr...

Mesoporous sulfonic acid silicas for pyrolysis bio-oil upgrading via acetic acid esterification

Manayil, Jinesh C.,Inocencio, Carlos V. M.,Lee, Adam F.,Wilson, Karen

, p. 1387 - 1394 (2016)

Propylsulfonic acid derivatised SBA-15 c...

Selective acetylation of alcohols and amines with ethyl acetate in the presence of H6[PMo9V3O40] as the catalyst

Heravi, Majid M.,Bakhtiari, Khadijeh,Javadi, Negar M.,Oskooie, Hossein A.,Bamoharram, Fatemeh F.

, p. 445 - 447 (2007)

Acetylation of various alcohols and benz...

ZWITTERIONIC CATALYSTS FOR (TRANS)ESTERIFICATION: APPLICATION IN FLUOROINDOLE-DERIVATIVES AND BIODIESEL SYNTHESIS

-

Paragraph 0013; 0028, (2021/01/29)

An amide/iminium zwitterion catalyst has...

Proton-exchanged montmorillonite-mediated reactions of hetero-benzyl acetates: Application to the synthesis of Zafirlukast

Yang, Lei,Chen, Xuan,Ni, Kaidong,Li, Yuansheng,Wu, Jianhong,Chen, Weilin,Ji, Yin,Feng, Lili,Li, Fei,Chen, Dongyin

supporting information, (2020/06/28)

Proton-exchanged montmorillonite (H-mont...

104-21-2 Process route

: 104-93-8
p-methylanizole

: 104-21-2
p-methoxybenzyl acetate

: 123-11-5
4-methoxy-benzaldehyde

: 100-09-4
4-methoxybenzoic acid

Conditions

Conditions	Yield
With oxygen; cobalt(II) acetate; In acetic acid; at 110 ℃; for 3h; under 2280 Torr;

: 3319-15-1
rac-1-(4-methoxyphenyl)-ethanol

: 104-21-2
p-methoxybenzyl acetate

: 100-06-1
1-(4-methoxyphenyl)ethanone

Conditions

Conditions	Yield
With ammonium peroxydisulfate; copper diacetate; sodium acetate; In acetic acid; at 100 ℃; for 0.5h; Yield given. Yields of byproduct given;
With ammonium peroxydisulfate; copper diacetate; In acetic acid; at 100 ℃; for 0.5h; Yield given. Yields of byproduct given;

104-21-2 Upstream products

104-93-8
p-methylanizole
15175-54-9
N,N-dimethyl-4-methoxylbenzylamine
108-24-7
acetic anhydride
105-13-5
4-Methoxybenzyl alcohol

104-21-2 Downstream products

105-13-5
4-Methoxybenzyl alcohol
130436-68-9
(4-methoxyphenethoxy)trimethylsilane
104-93-8
p-methylanizole
82101-69-7
1-methoxy-4-(methyl-d) benzene